| Title: |
Use of Sulfur Waste in the Production of Metakaolin-Based Geopolymers |
| Authors: |
Mazen Alshaaer; Abdulaziz O. S. Alanazi; Ibrahim M. I. Absa |
| Source: |
Sustainability, Vol 15, Iss 13608, p 13608 (2023) |
| Publisher Information: |
MDPI AG |
| Publication Year: |
2023 |
| Collection: |
Directory of Open Access Journals: DOAJ Articles |
| Subject Terms: |
sulfur; geopolymers; metakaolin; XRD; Environmental effects of industries and plants; TD194-195; Renewable energy sources; TJ807-830; Environmental sciences; GE1-350 |
| Description: |
This preliminary study introduces the incorporation and chemical stabilization of sulfur waste into a geopolymer matrix and explores the concept of material production for further environmental and engineering solutions. In this study, a novel synthesis procedure for sulfur-based geopolymers was introduced, and the role of sulfur in geopolymers and its optimal content to obtain a stable structure were explored. Geopolymers were synthesized by dissolving sulfur in an alkaline activator in different proportions. The alkaline solution was then mixed with metakaolin to synthesize the geopolymer matrix. Adding sulfur in amounts from 0 wt.% to 5 wt.%, compared with metakaolin, led to an increase in the compressive strength of the geopolymers from 22.5 MPa to 29.9 MPa. When sulfur was between 5 wt.% and 15 wt.%, a decrease in the compressive strength was observed to 15.7 MPa, which can be explained by defects and voids in the geopolymer’s microstructure due to the solubility of excess sulfur. Because of the incorporation of sulfur into the geopolymers, a compact and dense microstructure was formed, as reported in the SEM analysis. An XRD analysis showed that, besides quartz and analcime, a new phase, A l2 ·H 10 ·O 17 ·S 3 , was also formed as a result of sulfur dissolution in the alkaline activator of the geopolymers. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| Relation: |
https://www.mdpi.com/2071-1050/15/18/13608; https://doaj.org/toc/2071-1050; https://doaj.org/article/8c66fcec0f8d4e21a3b5e8ec3c2ccc9b |
| DOI: |
10.3390/su151813608 |
| Availability: |
https://doi.org/10.3390/su151813608; https://doaj.org/article/8c66fcec0f8d4e21a3b5e8ec3c2ccc9b |
| Accession Number: |
edsbas.DC008AAC |
| Database: |
BASE |