| Title: |
InterCarb: A Community Effort to Improve Interlaboratory Standardization of the Carbonate Clumped Isotope Thermometer Using Carbonate Standards |
| Authors: |
Bernasconi, Stefano M.; Daëron, Mathieu; Bergmann, Kristin D.; Bonifacie, Magali; Meckler, Anna Nele; Affek, Hagit P.; Anderson, Noah T.; Bajnai, David; Barkan, Eugeni S.; Beverly, Emily J.; Blamart, Dominique; Burgener, Landon K.; Calmels, Damien; Chaduteau, Carine; Clog, Matthieu; Davidheiser-Kroll, Brett; Davies, Amelia J.; Dux, Florian W.; Eiler, John M.; Elliott, Ben M.; Fetrow, Anne C.; Fiebig, Jens; Goldberg, Samuel L.; Hermoso, Michaël; Huntington, Katharine W.; Hyland, Ethan G.; Ingalls, Miquela; Jaggi, Madalina; John, Cédric Michaël; Jost, Adam B.; Katz, Sarah; Kelson, Julia R.; Kluge, Tobias M.; Kocken, Ilja J.; Laskar, Amzad Hussain; Leutert, Thomas J.; Liang, D.; Lucarelli, Jamie, Kaaren; Mackey, Tyler J.; Mangenot, Xavier; Meinicke, Niklas; Modestou, Sevasti; Müller, Inigo A.; Murray, Sean T.; Neary, Ashling; Packard, Natalie; Passey, Benjamin H.; Pelletier, Elise M.; Petersen, Sierra V.; Piasecki, Alison M.; Schauer, Andrew J.; Snell, Kathryn; Swart, Peter Koenraad; Tripati, Aradhna K.; Upadhyay, Deepshikha; Vennemann, Torsten; Winkelstern, Ian Z.; Yarian, Drake A.; Yoshida, Naohiro; Zhang, Naizhong; Ziegler, Martin |
| Contributors: |
Geological Institute ETH Zürich; Department of Earth Sciences Swiss Federal Institute of Technology - ETH Zürich (D-ERDW); Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology Zürich (ETH Zürich)-Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology Zürich (ETH Zürich); Laboratoire des Sciences du Climat et de l'Environnement Gif-sur-Yvette (LSCE); Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA); Paléocéanographie (PALEOCEAN); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)); Department of Earth, Atmospheric and Planetary Sciences MIT, Cambridge (EAPS); Massachusetts Institute of Technology (MIT); Institut de Physique du Globe de Paris (IPG Paris); Bjerknes Centre for Climate Research (BCCR); Department of Biological Sciences Bergen (BIO / UiB); University of Bergen (UiB)-University of Bergen (UiB); Institute of Earth Sciences Jerusalem; The Hebrew University of Jerusalem (HUJ); Institute of Geosciences Frankfurt am Main; Goethe University Frankfurt = Goethe-Universität Frankfurt am Main; Department of Earth and Atmospheric Sciences Houston; University of Houston; Department of Earth and Environmental Sciences Ann Arbor; Université du Michigan = University of Michigan Ann Arbor (UMich); Department of Marine, Earth, and Atmospheric Sciences NCSU (MEAS); North Carolina State University Raleigh (NC State); University of North Carolina System (UNC)-University of North Carolina System (UNC); Institut de Physique du Globe de Paris (IPGP - UMR_7154); Institut national des sciences de l'Univers (INSU - CNRS)-Institut National de l'Information Géographique et Forestière IGN (IGN)-Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité); Géosciences Paris Saclay (GEOPS); Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS); Scottish Universities Environmental Research Centre (SUERC); University of Glasgow-The University of Edinburgh; University of Colorado Boulder; Stockholm University; Imperial College London; University of Wollongong Australia; School of Geography Melbourne; Faculty of Science Melbourne; University of Melbourne-University of Melbourne; Caltech Division of Geological and Planetary Sciences; California Institute of Technology (CALTECH); Department of Earth, Planetary and Space Sciences Los Angeles (EPSS); University of California Los Angeles (UCLA); University of California (UC)-University of California (UC); Laboratoire d’Océanologie et de Géosciences (LOG) - UMR 8187 (LOG); Institut national des sciences de l'Univers (INSU - CNRS)-Université du Littoral Côte d'Opale (ULCO)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD Ile-de-France ); University of Washington Seattle; Penn State Department of Geosciences; Pennsylvania State University State College, PA (Penn State); Penn State System-Penn State System; Karlsruhe Institute of Technology = Karlsruher Institut für Technologie (KIT); Department of Earth Sciences Utrecht; Universiteit Utrecht / Utrecht University Utrecht; Institute of Earth Sciences Tapei (IES Sinica); Academia Sinica; Max Planck Institute for Chemistry (MPIC); Max-Planck-Gesellschaft; Department of Earth and Planetary Sciences Albuquerque (EPS); The University of New Mexico Albuquerque; New Mexico Consortium (NMC)-New Mexico Consortium (NMC); Macquarie University Sydney; Dartmouth College Hanover; University of Miami; Institut des Dynamiques de la Surface Terrestre = Institute of Earth Surface Dynamics (IDYST); Université de Lausanne = University of Lausanne (UNIL); Grand Valley State University (GVSU); Earth-Life Science Institute Tokyo (ELSI); Tokyo Institute of Technology Tokyo (TITECH); National Institute of Information and Communications Technology Tokyo (NICT); 1156134, 1713275, 1933130, 206021‐164032 National Science Foundation, NSF: 1925973 David and Lucile Packard Foundation, DLPF National Aeronautics and Space Administration, NASA: 80NSSC19K0464 Basic Energy Sciences, BES: DE‐FG02‐13ER16402 University of Michigan, U-M: 1854873, 724097 University of Colorado Boulder: 1524785 North Carolina State University, NCSU Horizon 2020 Framework Programme, H2020: 638467 Trond Mohn stiftelse European Research Council, ERC Japan Society for the Promotion of Science, KAKEN: JP17H06105 Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung, SNF: 200020_160046, 200021_143485 Eidgenössische Technische Hochschule Zürich, ETH Nederlandse Organisatie voor Wetenschappelijk Onderzoek, NWO: 016.161.365 Israel Science Foundation, ISF: 1000/16, 171/16, DE‐SC0016561 Institut national des sciences de l'Univers, INSU,CNRS Centre National de la Recherche Scientifique, CNRS Qatar Science and Technology Park, QSTP Institut de Physique du Globe de Paris, IPGP; S. M. Bernasconi acknowledges instrumentation funding from ETH Zürich and support from Swiss National Science Foundation grants 200021_143485, 200020_160046. M. Daëron acknowledges the clumped‐isotope facility at LSCE is part of PANOPLY (Plateforme Analytique Géosciences Paris‐Saclay) and was supported by the following institutions: Région Ile‐de‐France; Direction des Sciences de la Matière du Commissariat à l’Energie Atomique; Institut National des Sciences de l’Univers, Centre National de la Recherche Scientifique; Universtité de Versailles/Saint‐Quentin‐en‐Yvelines. K. D. Bergmann and the MIT carbonate clumped isotope facility acknowledge support from the Packard Foundation, the Agouron Foundation and NASA Exobiology Grant 80NSSC19K0464. M. Bonifacie acknowledges the program Emergences Ville de Paris for early funding that allowed building her clumped isotope laboratory at Institut de Physique du Globe de Paris. M. Bonifacie also thanks IPGP and Université de Paris for support for the organization of the VIth Clumped Isotope Workshop in Paris in 2017. Funding was provided to C. M. John and the Imperial College Clumped Isotope Laboratory by Qatar Petroleum, Shell, and the Qatar Science and Technology Panel. Funding was provided to K. W. Huntington at University of Washington from NSF EAR grants 1933130, 1713275, and 1156134. T. Vennemann acknowledges the support of the Swiss National Science Foundation grant 206021‐164032. A. N. Meckler acknowledges funding from the Trond Mohn Foundation and the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement no. 638467). Funding was provided to the Tripati Laboratory at UCLA for these analyses from DOE BES grant DE‐FG02‐13ER16402. Funding was provided to the Hyland Laboratory at NCSU for these analyses from NSF EAR‐FRES grant 1925973. Funding was provided to the Yoshida Laboratory at Tokyo Tech. for these analyses from JSPS grant JP17H06105. Funding was provided to the CLIMB Lab at the University of Bergen for these analyses by the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement No 638467) and by the Trond Mohn Foundation. Funding was provided to the UU Clumped Laboratory at Utrecht University by the Netherlands Research Organization (NWO) through VIDI grant 016.161.365. Funding was provided to the CUBES‐SIL at CU Boulder by startup funds from the University of Colorado Boulder and NSF EAR grant 1524785. The UM SCIPP Laboratory was supported by startup funds from the University of Michigan. J. R. Kelson was supported by NSF PRF grant 1854873. HPA acknowledges support by ERC (Grant no.724097) and ISF (Grant no. 171/16 and 1000/16). Funding was provided to the Eiler lab at Caltech from the DOE BES program, award number DE‐SC0016561.; ANR-17-CE01-0004,CARCLIM,Les coccolithophoridés : acteurs et enregistreurs des changements climatiques(2017); European Project: 638467,ERC-2014-STG,ERC-2014-STG,C4T(2015); European Project: 0724097(2007) |
| Source: |
EISSN: 1525-2027 ; Geochemistry, Geophysics, Geosystems ; https://hal.science/hal-03256441 ; Geochemistry, Geophysics, Geosystems, 2021, Clumped Isotope Geochemistry: From Theory to Applications, 22 (5), pp.e2020GC009588. ⟨10.1029/2020GC009588⟩ |
| Publisher Information: |
CCSD; AGU and the Geochemical Society |
| Publication Year: |
2021 |
| Collection: |
Université de Versailles Saint-Quentin-en-Yvelines: HAL-UVSQ |
| Subject Terms: |
carbonate; clumped isotopes; interlaboratory calibration; mass spectrometry; reference materials; [SDU.STU]Sciences of the Universe [physics]/Earth Sciences |
| Description: |
International audience ; Increased use and improved methodology of carbonate clumped isotope thermometry has greatly enhanced our ability to interrogate a suite of Earth-system processes. However, interlaboratory discrepancies in quantifying carbonate clumped isotope (Δ47) measurements persist, and their specific sources remain unclear. To address interlaboratory differences, we first provide consensus values from the clumped isotope community for four carbonate standards relative to heated and equilibrated gases with 1,819 individual analyses from 10 laboratories. Then we analyzed the four carbonate standards along with three additional standards, spanning a broad range of δ47 and Δ47 values, for a total of 5,329 analyses on 25 individual mass spectrometers from 22 different laboratories. Treating three of the materials as known standards and the other four as unknowns, we find that the use of carbonate reference materials is a robust method for standardization that yields interlaboratory discrepancies entirely consistent with intralaboratory analytical uncertainties. Carbonate reference materials, along with measurement and data processing practices described herein, provide the carbonate clumped isotope community with a robust approach to achieve interlaboratory agreement as we continue to use and improve this powerful geochemical tool. We propose that carbonate clumped isotope data normalized to the carbonate reference materials described in this publication should be reported as Δ47 (I-CDES) values for Intercarb-Carbon Dioxide Equilibrium Scale. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| Relation: |
info:eu-repo/grantAgreement//638467/EU/Climate change across Cenozoic cooling steps reconstructed with clumped isotope thermometry/C4T; info:eu-repo/grantAgreement//0724097/EU/NEESR-II: Behavior and Design of Cast-in-Place Anchors under Simulated Seismic Loading/ |
| DOI: |
10.1029/2020GC009588 |
| Availability: |
https://hal.science/hal-03256441; https://hal.science/hal-03256441v1/document; https://hal.science/hal-03256441v1/file/2020GC009588.pdf; https://doi.org/10.1029/2020GC009588 |
| Rights: |
https://about.hal.science/hal-authorisation-v1/ ; info:eu-repo/semantics/OpenAccess |
| Accession Number: |
edsbas.EADD9D06 |
| Database: |
BASE |