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The origin of the oxygen bonded in soot particles in biofuel combustion: The ethanol case

Title: The origin of the oxygen bonded in soot particles in biofuel combustion: The ethanol case
Authors: Sirignano, M.; Esposito, V.; Oliano, M. M.; Apicella, B.; Russo, C.
Contributors: Sirignano, M.; Esposito, V.; Oliano, M. M.; Apicella, B.; Russo, C.
Publication Year: 2026
Collection: IRIS Università degli Studi di Napoli Federico II
Subject Terms: Ethanol; oxy-PAH; PAH; Particulate matter; Premixed flame
Description: This study investigates the origin of oxygen in soot particles formed during ethanol combustion. Carbon particulate matter (PM) and flame structure were analyzed in fuel-rich ethylene and ethanol-doped (20 %) flames. Gas-phase composition was assessed using probe sampling and gas chromatography, revealing that ethanol addition had minimal impact on CO, CO2, and C2H2 formation but reduced methane and C3-C6 hydrocarbons concentration. PM was sampled at different formation stages and the total sample was analyzed using laser desorption ionization-time of flight mass spectrometry (LDI-TOFMS). A Fast Fourier Transform (FFT) approach was applied to interpret complex mass spectra. Three PM fractions were also examined: species
Document Type: article in journal/newspaper
Language: English
Relation: volume:405; journal:FUEL; https://hdl.handle.net/11588/1032897
DOI: 10.1016/j.fuel.2025.136490
Availability: https://hdl.handle.net/11588/1032897; https://doi.org/10.1016/j.fuel.2025.136490
Rights: info:eu-repo/semantics/openAccess ; license:Creative commons ; license uri:http://creativecommons.org/licenses/by/4.0/
Accession Number: edsbas.EB702B6
Database: BASE