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Ppb detection level’s hydrogen sensor using a SPR grating in the triggered switching configuration

Title: Ppb detection level’s hydrogen sensor using a SPR grating in the triggered switching configuration
Authors: Giraud, Pascal; Varenne, Christelle; Brunet, Jérôme; Ndiaye, Amadou; Celle, Frédéric; Turover, Daniel; Bruhier, Hugo; Pacha, Salma Rajab; Meyer, Arnaud; Jourlin, Yves; Girault, Irvin; Gaté, Valentin; Arnould, Frédéric; Verrier, Isabelle
Contributors: Laboratoire Hubert Curien (LabHC); Institut d'Optique Graduate School (IOGS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS); Institut Pascal (IP); Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Institut national polytechnique Clermont Auvergne (INP Clermont Auvergne); Université Clermont Auvergne (UCA)-Université Clermont Auvergne (UCA); SILSEF SAS; Laboratoire Traitement du Signal et Instrumentation; Université Jean Monnet - Saint-Étienne (UJM); Laboratoire de Traitement du Signal et Instrumentation, Université Saint Etienne, 23, rue du Dr. Paul Michelon, F-42023 Saint-Etienne, France; Région Auvergne-Rhône-Alpes (Projet CAPTHY, Pack Ambition Recherche 2021-2024); ANR-18-CE04-0008,CAPTAIN,Capteurs Optiques pour la surveillance de la qualité de l'air(NO2, O3)(2018); ANR-17-EURE-0026,SLEIGHT,MANUTECH Surfaces Light EngineerinG Health & Society(2017)
Source: ISSN: 1094-4087 ; Optics Express ; https://hal.science/hal-05301084 ; Optics Express, 2025, 33 (14), pp.29648. ⟨10.1364/OE.561549⟩.
Publisher Information: CCSD; Optical Society of America - OSA Publishing
Publication Year: 2025
Collection: Université Jean Monnet – Saint-Etienne: HAL
Subject Terms: [PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]
Description: International audience ; An optical plasmonic hydrogen sensor is proposed, based on what we believe to be a novel configuration named plasmon-triggered switching. This configuration, involving two propagative orders diffracted by a deep metallic grating combined to a hydrogen-sensitive layer, is capable of measuring hydrogen concentrations. The two diffracted orders enable a differential measurement, which estimates a change of refractive index through evolution of the relative diffraction efficiency of each order at fixed wavelength and fixed angle, while cancelling any drift of the input laser source and other disturbances and allowing both a high sensitivity and a very low limit of detection (LOD). Experimental results, using a simple implementation involving one laser and two detectors, demonstrate a LOD without any signal post-processing, below 0.2 ppm (2.10 −5 % Vol) in filtered air, are in good agreement with simulations and exhibit very good repeatability. The proposed setup represents a very promising, compact and cost-efficient approach to real-time hydrogen sensing using a thin H 2 sensitive and selective palladium thin layer deposited on a gold grating for highly sensitive plasmon coupling.
Document Type: article in journal/newspaper
Language: English
DOI: 10.1364/OE.561549
Availability: https://hal.science/hal-05301084; https://hal.science/hal-05301084v1/document; https://hal.science/hal-05301084v1/file/OpticsExpress_20250605.pdf; https://doi.org/10.1364/OE.561549
Rights: info:eu-repo/semantics/OpenAccess
Accession Number: edsbas.F570E541
Database: BASE