In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes
| Title: | In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes |
|---|---|
| Authors: | Liautard, Virginie; Delgado, Marine; Colin, Boris; Chabaud, Laurent; Michaud, Guillaume; Pucheault, Mathieu |
| Contributors: | Institut des Sciences Moléculaires (ISM); Université Montesquieu - Bordeaux 4-Université Sciences et Technologies - Bordeaux 1 (UB)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS); Bostik Smart Technology Centre (BOSTIK); Arkema (Arkema) |
| Source: | ISSN: 1359-7345. |
| Publisher Information: | HAL CCSD; Royal Society of Chemistry |
| Publication Year: | 2022 |
| Collection: | Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
| Subject Terms: | [CHIM.ORGA]Chemical Sciences/Organic chemistry |
| Description: | International audience ; Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields. |
| Document Type: | article in journal/newspaper |
| Language: | English |
| Relation: | hal-03834829; https://hal.science/hal-03834829; https://hal.science/hal-03834829/document; https://hal.science/hal-03834829/file/CC_V1.pdf |
| DOI: | 10.1039/D1CC06390A |
| Availability: | https://hal.science/hal-03834829; https://hal.science/hal-03834829/document; https://hal.science/hal-03834829/file/CC_V1.pdf; https://doi.org/10.1039/D1CC06390A |
| Rights: | info:eu-repo/semantics/OpenAccess |
| Accession Number: | edsbas.F895C4EF |
| Database: | BASE |